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For the half cell
1.42 V
1.36 V
1.2V
1.3V
A hydrogen electrode placed in a buffer solution of and acetic acid in the ratio’s x: y and y : x has electrode potential values volt and volts respectively at . The pKa values of acetic acid is ( and are oxidation potential)
A cell with two electrodes, one of grey tin and the other white tin, both dipping in solution of showed zero e.m.f at What conclusion may be drawn form this
The e.m.f developed at the electrode solutions phase boundary concels the normal e.m.f
electrode surface develops a protective layer and the cell develops a very large internal resistance
Grey tin being non- metallic ceases to provide a reversible electro reaction
The free energy change of the cell becomes zero .
b
a
c
d
Two liquids A and B have vapour pressure in the ratio at a certain temperature Assume A and B form an ideal solution and the ratio of mole fractions of A to B in the vapour phase is 1:3 , then the mole fraction of A in the solution at the same temperature
A certain solution of benzoic acid and in benzene has a freezing point depression of and boiling point elevation of Thus select the correct statement. Statement I -:there is dimer formation when undergoing freezing
Statement II -there is no change when undergoing boiling
Statement III: -:reverse of I and II freezing formation in freezing and boiling state
Statement IV: -:dimer formation in freezing and boiling state
only I
II, III
I, II
III, IV
f the internal energy of an ideal gas decreases by the same amount as the work done by the system, the process is
isothermal
isolated
adiabatic
cyclic
40 Joules of heat has been given to a system and the work done by the system is equal to –8 joules . Evaluate the increase in internal energy by the system
8J
48J
None
56 J
In thermodynamics a process is called reversible when
The system changes into the surroundings spontaneously.
Surrounding and system change into each other
The surroundings are always is equilibrium with the system
here is no boundary between system and surroundings
Latent heat of vaporization of water is . The entropy change during the evaporation of 1 mole of water at is
Entropy of universe, in the case of adiabatic expansion of a gas is
Which of the following statement is not true
NaCl has 6:6 co- ordination while CsCl has 8:8 co- ordinations
NaCl structure on heating transforms to CsCl structure
In structure each F- ion is coordinated by four ions and each ion is co- ordinated by eight F- ions
In , each oxide ion is co- ordinates by eight ions and each ion by four oxide ions
In a face – centered arrangement of A and B atoms. Where A atoms are at the corners of the unit cell and B atoms at the face centres . One of the A atoms is missing from one corner in each unit cell. The simplest formula of the compound will be
In a solid oxide ions are arranged in ccp. cations A occupy of the tetrahedral voids and cations B occupy of the octahedral voids. The formula of the compounds is
Which plot is the adsorption isobar for chemisorption where x is the amount of gas adsorbed on mass M ( at constant pressure ) at temperature T
The oxidation of oxalic acid by acidified becomes fast as the reaction progresses due to
presence of
auto catalysis by
Which is not the property of the hydrophillic sols
the charge of the particle depends upon pH values of the dispersion medium.
coagulation is reversible
high concentration of dispersed phase can be easily attained
viscosity and surface tension are about the same as of dispersed medium.
A
B
Both correct
None of correct
Which graph represents the variation of photon momentum ‘P’ with wavelength
A viral preperation was inactivated in a chemical bath. The inactivation process was found to be first order in virus concentration, and at the beginning of the experiment 2.0% of the virus has found to be inactivated per minute. Hence rate constant for the inactivated process is
It is easier to liquefy oxygen than hydrogen because :
Oxygen has a higher critical temperature and lower inversion temperature than hydrogen
the critical temperature and inversion temperature of oxygen is very low.
Oxygen has a lower critical temperature and higher inversion temperature , than hydrogen
oxygen has a higher critical temperature and a higher inversion temperature than hydrogen
The correct order of acidic strength is
An ideal gas undergoes isothermal expansion followed by heat removal at constant volume and then by heat removal at constant pressure to the initial volume. The correct description of these steps is indicated by
Which one of the following graphs correctly represents the change in electrical conductivity as copper (II) carbonate is gradually added to dilute sulphuric acid
A chemical reaction proceeds as . The progress of reactions as :represented as which of following step is fast
In general , the configuration of lanthanones is . it is observed that with increase in atomic number of lanthanides, there is decrease of ionic radii from to . The reason for decrease in ionic radii is increase in
Atomic volume
Electronegtivity
Nuclear attraction for valence electrons leading to inwards shrinking of shells
Valency electron
The sudden jump between of second and third ionisation energies of an atom would be associated with the electronic configuration
The complex in which the number of unpaired electrons is zero
None of these
The atomic number of potassium is 19 and that of maganese is 25. Although [] has a dark violet colour, that is colourless. This is due to fact that
Mn is a transition element , while K is not
The Mn is a high positive oxidation state and allows charge transfer transition
The effective atomic number of in is 26 while for the effective atomic no. is 18
Mercury is the only metal which is liquid at . This is due to
Low ionisation potential
High atomic weight
High vapour pressure
Very high ionisation energy and weak metallic bond
Electrolyte reduction of alumina to aluminum by Hall- Heroult process is carried out
In the presence of NaCl
In the presence of fluorite
In the presence of cryolite which forms a melt with lower melting point
In the presence of cryolite which forms a melt with higher melting point
For making in the laboratory
Which of the following statement is not correct
Nascent hydrogen can never be isolated but atomic hydrogen can be isolated
Atomic hydrogen reduces to and to
The reducing power of nascent hydrogen is more than that of atomic hydrogen
The ortho and para hydrogen have
Different physical properties but same chemical properties
Same physical properties but differnt chemical properties
Different physical and chemical properties
Same physical properties and chemical properties
The hair dyes available in the market generally contain two bottles, one containing the dye and the other hydrogen peroxide. Before applying the dye, the two solution are mixed . The hydrogen peroxide
Acidifies the solution of the dye
Reduces the dye to give the desired colour
Oxidizes the dye to give the desired colour
is added to dilute the solution of the dye
The deep colour produced when iodine is dissolved in a solution of potassium iodide is caused by the presence of
The hydride ion is stronger base than its hydroxide, which of the following reaction will occur if sodium hydride is dissolved in water
All
The correct order of solubility of fluorides of alkaline earth metals is
Consider the following points and select wrong statement
In alkali metals , , and lithium has the minimum value of M.P
The density of potassium is less than sodium
Least mobile ion is
Which of the following is wrong
The solubility’s of sulphates and carbonates decreases with increases in atomic number of the alkaline earth metals
The complex formation ability decreases from Be to Ba
Reducing character of alkaline earth metals increases from Be to Ba
Yellow – coloured solution of changes to light green colour when
A:- gas is passed B:- is added C:- is added D:- is added
CD
AB
C
AC
ABCD
3 planar triangular and 2 tetrahedral units
5 planer triangular units only
2 planar triangular and 2 tetrahedral units
no such units
Which of the following statements is / are correct A:- and are used as bleaching agents paper pulp and textiles. B:- salts are used as sterilising agents C:- disproportionates in alkaline medium D:- oxdised to by in acidic medium
ABC
BCD
AD
Density of nitrogen gas prepared from air is slightly greater than that of nitrogen prepared by chemical reaction from a compound of nitrogen because aerial nitrogen contains
Greater amount of molecules derived from isotope
Some molecules analogous to
A gas does not turn lime –water milky , supports the combustion of burning magnesium. it has no smell and is colourless. it extinguishes a glowing splint but under some circumstnces reacts with oxygen and hydrogen it is not poisonous . The gas is likely to be
Nitrogen
Carbon dioxide
Helium
Water vapour
Which of the following statements is / are correct A:- Compounds of S, Se and Te with oxygen are generally tetravelent, but fluorine brings out of maximum oxidation state of +6 B:- The higher oxidation states become less stable as we go down the group C:- The +4 state shows both oxidizing and reducing properties , but in +6 state the compounds are only oxidizing D:- These compounds are typically volatile
DA
Redox change
Solubility product
Common ion effect
When is added to an acidified solution of
Solution turns yellow due to formations of
A deep blue – violet coloured compounds is formed
Solution gives green ppt. of
Solution turns green due to formations of
Which of the following statements is correct
In acidic solution ion dimerises to from chromate in ,
The chromate ion, is a common anion in neutral or alkaline solution
Dichromate ion is a very strong oxidising agent and get reduce to ion
Select the correct statement
IUPAC name for is tetrammine chloronitrocobalt (III) chloride
A square planar complex represented will show
Geometrical isomers
Linkage isomerism
No isomerism
Optical isomerism
Which of the following are expected to be paramagnetic?
A co – ordination compound of platinum chloride and ammonia gives a white precipitate with and on ionization gives four ions. Its formula is
A pale green crystalline in organic salt (x) dissolved freely in water , It gives a brown precipatate on addition of aqueous . The solution of (x) also gives a black precipitate on bubbling in alkaline medium . An aqueous solution of (x) decolourizes the pink colour of the permanganate solution. The metal in the salt solutions is
Copper
Iron
Aluminum
Lead
The blue colour obtained by the addition of excess dil. to an aqueous solution of a salt containing
On treatment with Kl, mercuric chloride gives a product X which is soluble in excess KI to form another product Y, X and Y are
Select correct statement
both correct
none of correct
When a substance A reacts with water it produces a combustible gas B and a solution of substance C in water . When another D reacts with this solution of C, it also produces the same gas B on warming but D can produce gas B on reaction with dilute sulphuric acid at room temperature A imparts a deep golden yellow colour to a smokeless flame of Bunsen burner , A, B,C and D respectively are
The IUPAC name of the compound
2- methyl pent-3-yne –3- ene
2- methyl pent-2-ene –3- yne
2- methyl pent-1-ene –3- yne
4- methyl pent-4-ene –2- yne
The eclipsed and staggered conformation of ethane due to
Free rotation about C – C single bond
Absence of rotation about C – C bond
Restricted rotation about C – C single bond
None of the above
The two isomers given below are
Position isomers
Diastereomers
Enantiomers
Regiomers
Which of the following statement about optical activity is incorrect :
Essential condition for a compound to exhibit optical isomerism is that the mirror images are super imposable
A molecule with an asymmetric carbon atom has stereoisomers, which are optically active
Essential condition for a compounds to exhibit optical isomerism is that the mirror images are super imposable
Essential condition for compounds to exhibit optical isomerism is that there should be dissymmetry in the molecule.
In the following compounds The order of basicity is :
I > III > II > IV
II > I > III > IV
IV > I > III > II
III > I > IV > II
mixture of both A and B
Among these, which of the following is correct order of the extent of aromaticity
III > II > I
I > III > II
I> II > III
III > I > II
Which is true about this reaction
P is meso 1,2 butan –di –ol formed by syn addition
P is a racemic mixture of 1,2, butan di-0l formed by syn addition
P is recemic mixture of d and I , 1,2 butan –diol formed by anti addition
P is meso 1,2 butan – di –ol formed by anti addition
The correct order of basicity of following compounds is
i> ii>iii > iv
i> iii> ii > iv
iii> i > ii> iv
ii >i > iii > iv
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One mole of an organic compound ‘A’ , in capable of showing steroisomerism reacts with only one mole of on Hydrogenation over Pd, A undergoes ozonolysis to form a symmetolcas diketane . Teh compundA’ is :
Which of the following methods can be used for the preparation of acetylene?
Which of the following statements are correct:
Jones reagent, which is chromic acid in aqueous acetone solution oxidises alcohol to aldehyde and alcohol to ketone but does not effect double bound
All are correct
Chromic acid oxidises alcohols to carboxylic acid
Which of the following compound will fail to give the haloform reaction
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